基于三氮唑类化合物的金属卡宾形成反应研究进展
收稿日期: 2016-01-29
修回日期: 2016-02-28
网络出版日期: 2016-03-18
基金资助
国家自然科学基金（No.21462022）资助项目.
Advances on the Metallocarbene Formation Reactions Based on Triazole Derivatives
Received date: 2016-01-29
Revised date: 2016-02-28
Online published: 2016-03-18
Supported by
Project supported by the National Natural Science Foundation of China (No. 21462022).
黄家翩 , 周豪 , 陈知远 . 基于三氮唑类化合物的金属卡宾形成反应研究进展[J]. 有机化学, 2016 , 36(7) : 1555 -1563 . DOI: 10.6023/cjoc201601042
Carbenes are very useful key intermediates in organic synthesis, which generally display high reactivity in chemical transformations. Metallocarbenes can be regarded as metal stabilized organic carbenes. The research progress of the metallocarbene formation and the related reactions based on triazole compounds are reviewed in this work. The RhII-catalyzed metallocarbenes derived from N-sulfonyl-1,2,3-triazoles, as well as the subsequent insertion reactions into other reaction systems to generate new C-C or C-hetero bonds, are specially focused.
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