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2016 , Vol. 36 >Issue 8: 1937 - 1941

DOI: https://doi.org/10.6023/cjoc201603024

研究简报

新型水溶性圆柱形大三环主体与联吡啶盐的络合性能研究

  • 曾飞 ,
  • 唐琳俐 ,
  • 陈小明 ,
  • 李治章 ,
  • 韩莹 ,
  • 陈传峰
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  • a 湖南科技学院化学与生物工程学院 湘南优势植物资源综合利用湖南省重点实验室 永州 425199;
    b 中国科学院化学研究所 分子识别与功能院重点实验室 北京 100190

收稿日期: 2016-03-15

  修回日期: 2016-03-30

  网络出版日期: 2016-04-15

基金资助

湖南省高校科技创新团队及湖南省有机化学重点学科（2016）资助项目.

收起

Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

  • Zeng Fei ,
  • Tang Linli ,
  • Chen Xiaoming ,
  • Li Zhizhang ,
  • Han Ying ,
  • Chen Chuanfeng
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  • a Key Laboratory Comprehensive Utilization of Dominant Plants Resources in South Hunan, Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou 425199;
    b CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190

Received date: 2016-03-15

  Revised date: 2016-03-30

  Online published: 2016-04-15

Supported by

Project supported by the Sci-Tech Innovation Teams in Universities of Hunan Province and the Construct Program of the Key Discipline in Hunan Province (2016).

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摘要

描述了新型水溶性圆柱形大三环主体与联吡啶盐客体在水溶液中与固体下的络合性质，表明大三环主体与联吡啶盐能够形成1：1的超分子络合物. 此外，主客体络合物的形成与解离还可以通过酸碱的加入进行可逆调控，并且该过程也可通过肉眼进行观察.

关键词： 大三环主体; 联吡啶盐; 络合作用; 酸碱调控

本文引用格式

曾飞 , 唐琳俐 , 陈小明 , 李治章 , 韩莹 , 陈传峰 . 新型水溶性圆柱形大三环主体与联吡啶盐的络合性能研究[J]. 有机化学, 2016 , 36(8) : 1937 -1941 . DOI: 10.6023/cjoc201603024

Abstract

The complexation between the novel water-soluble cylindrical macrotricyclic host and paraquat guests in both solution and solid state was investigated in detail. It was found that the host could form 1:1 complexes with paraquat salts in water solution and solid state. Interestingly, the complexation and decomplexation of the complexes between the host and the guest could be achieved by changing the pH of the solution, and the process could also be observed by naked eye.

Key words： macrotricyclic host; paraquat; complexation; acid-base controlled

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