磷亲核试剂对缺电子烯烃不对称共轭加成反应的进展
收稿日期: 2016-02-19
修回日期: 2016-04-20
网络出版日期: 2016-04-29
基金资助
国家自然科学基金（Nos. 20902099，21172238，21472218）资助项目.
Recent Advances in the Asymmetric Conjugate Addition Reactions of Phosphorus Nucleophiles to Electron-Deficient Alkenes
Received date: 2016-02-19
Revised date: 2016-04-20
Online published: 2016-04-29
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 20902099, 21172238, 21472218).
李振 , 段伟良 . 磷亲核试剂对缺电子烯烃不对称共轭加成反应的进展[J]. 有机化学, 2016 , 36(8) : 1805 -1813 . DOI: 10.6023/cjoc201602018
Chiral phosphines are very useful in the fields of asymmetric catalysis, pharmaceutical chemistry, and materials. These compounds have been used as ligands coordinated to transition metals or organocatalysts in various reactions to furnish optically active products with high efficiency. Asymmetric phosphorus-addition reaction can be utilized for the direct preparation of chiral phosphorus compounds. This review summarizes the recent progress in the field of enantioselective phosphorus-addition reactions. Several examples of transition metal- and organocatalyst-promoted asymmetric hydrophosphination reactions of electron-deficient alkenes have been introduced.
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