ABC三嵌段共聚物的聚合诱导自组装研究
收稿日期: 2016-05-14
修回日期: 2016-05-22
网络出版日期: 2016-05-24
基金资助
国家自然科学基金（Nos.51573046、51622301）、中央高校基本科研专项资金（Nos.B14018、WD1213002）、上海市曙光学者计划（No.14SG29）资助项目.
Polymerization-Induced Self-Assembly of ABC Triblock Copolymer
Received date: 2016-05-14
Revised date: 2016-05-22
Online published: 2016-05-24
Supported by
Project supported by the National Natural Science Foundation of China (Nos.51573046, 51622301), the Fundamental Research Funds for the Central Universities (Nos.B14018, WD1213002) and the Project of Shanghai Municipality (No.14SG29).
黄锋, 徐鹏翔, 吕翌晟, 林绍梁 . ABC三嵌段共聚物的聚合诱导自组装研究[J]. 有机化学, 2016 , 36(9) : 2220 -2224 . DOI: 10.6023/cjoc201605023
Polymerization-induced self-assembly (PISA) is a new robust strategy to produce concentrated dispersions of block copolymer nano-objects. Insight into the dynamic process can promote the development of PISA by computer simulations. In this work, dissipative particle dynamics simulations (DPD) with a reaction model were employed to investigate the PISA behavior of ABC triblock copolymer. The polymerization of solvophobic B block was firstly performed using solvophilic macromolecular initiator A to fabricate AB copolymer. The continuous morphology transition from spherical micelle to wormlike micelle, to lamellae and finally to vesicle was observed during the process. Then, the polymerization of C block was further carried out and induced the different ABC triblock copolymer aggregates by tuning the interaction between C block and solvent (solvophobic or solvophilic).
Key words： polymerization; self-assembly; dissipative particle dynamics; simulation
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