碳酸银介导的芳胺氧化脱氢偶联制备芳香偶氮化合物
收稿日期: 2016-07-05
修回日期: 2016-08-17
网络出版日期: 2016-09-01
基金资助
上海市科学自然基金（No. 15ZR1401400）以及中央高校教育基金（Nos. CUSF-DH-D-2016028，BCZD2016004）资助项目.
Ag2CO3 Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds
Received date: 2016-07-05
Revised date: 2016-08-17
Online published: 2016-09-01
Supported by
Project supported by the Natural Science Foundation of Shanghai Municipality(No. 15ZR1401400) and the Fundamental Research Funds for the Central Universities from the Ministry of Education of China(Nos. CUSF-DH-D-2016028, BCZD2016004).
安玉龙 , 谭鸿儒 , 赵圣印 . 碳酸银介导的芳胺氧化脱氢偶联制备芳香偶氮化合物[J]. 有机化学, 2017 , 37(1) : 226 -231 . DOI: 10.6023/cjoc201607007
Aromatic azo compounds are widely used as organic dyes,biological medicines,food additives,radical initiators and so on.This paper describes an efficient protocol for the synthesis of aromatic azo compounds from anilines via Ag2CO3 mediated oxidative dehydrogenative coupling reactions in the presence of(CH3)3COK in PhCl.The yields are up to 92%,and this method is easy-operation and provides a practical process to synthesize aromatic azo compounds under mild conditions.
Key words： anilines; Ag2CO3; (CH3)3COK; aromatic azo compounds
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