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2017 , Vol. 37 >Issue 4: 824 - 840

DOI: https://doi.org/10.6023/cjoc201611017

综述与进展

3-异硫氰酸酯氧化吲哚参与的不对称串联反应研究进展

  • 谭芬 ,
  • 肖文精 ,
  • 曾国平
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  • a. 湖北第二师范学院 植物抗癌活性物质提纯与应用湖北省重点实验室 武汉 430205;
    b. 华中师范大学化学学院 农药与化学生物学教育部重点实验室 武汉 430079

收稿日期: 2016-11-15

  修回日期: 2016-12-21

  网络出版日期: 2017-01-04

基金资助

国家自然科学基金（No.21602052）、湖北省教育厅科学技术研究（No.Q20163004）资助项目.

收起

Recent Advances in 3-Isothiocyanato Oxindoles Engaged Asymmetric Cascade Reactions

  • Tan Fen ,
  • Xiao Wenjing ,
  • Zeng Guoping
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  • a. Hubei Key Laboratory of Purification and Application of Plant Anti-cancer Active Ingredients, Hubei University of Education, Wuhan 430205;
    b. Key Laboratory of Pesticide & Chemical Biology Ministry of Education and College of Chemistry, Central China Normal University, Wuhan 430079

Received date: 2016-11-15

  Revised date: 2016-12-21

  Online published: 2017-01-04

Supported by

Project supported by the National Natural Science Foundation of China (No. 21602052) and the Scientific Research Project of Hubei Provincial Department of Education (No. Q20163004).

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摘要

3-异硫氰酸酯氧化吲哚是一类高活性的新型反应试剂，已经被广泛地应用于串联反应中，并用于结构多样的手性螺环氧化吲哚骨架的构建. 简单综述了近六年来3-异硫氰酸酯氧化吲哚参与的几类串联环化反应的最新研究进展，主要介绍各反应的特点、活化模式及合成应用，并展望它的发展前景.

关键词： 3-异硫氰酸酯氧化吲哚; 螺环氧化吲哚; 不对称合成; 串联反应

本文引用格式

谭芬 , 肖文精 , 曾国平 . 3-异硫氰酸酯氧化吲哚参与的不对称串联反应研究进展[J]. 有机化学, 2017 , 37(4) : 824 -840 . DOI: 10.6023/cjoc201611017

Abstract

3-Isothiocyanato oxindoles have been widely employed as a class of highly reactive and novel reagents in the enantioselective synthesis of diverse spirooxindoles. This review summarizes the recent advances of 3-isothiocyanato oxindoles mediated some types of cascade process in the past six years, including properties of reaction, activation models and synthetic applications. Furthermore, the prospects of this concept are also discussed.

Key words： 3-isothiocyanato oxindole; spirooxindole; asymmetric synthesis; cascade reaction

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