铑催化烯基氮杂环丙烷与炔胺的立体专一性[3+2]环加成反应(封面文章)
收稿日期: 2017-01-21
修回日期: 2017-02-16
网络出版日期: 2017-02-20
基金资助
上海市扬帆计划（No.15YF1403600）和国家自然科学基金（Nos.21602062，21373088，21425205）资助项目.
Rhodium(Ⅰ)-Catalyzed Stereospecific [3+2] Cycloadditions of Vinylaziridines and Ynamides
Received date: 2017-01-21
Revised date: 2017-02-16
Online published: 2017-02-20
Supported by
Project supported by the Shanghai Sailing Program (No. 15YF1403600) and the National Natural Science Foundation of China (Nos. 21602062, 21373088, 21425205).
朱超泽 , 冯见君 , 张俊良 . 铑催化烯基氮杂环丙烷与炔胺的立体专一性[3+2]环加成反应(封面文章)[J]. 有机化学, 2017 , 37(5) : 1165 -1172 . DOI: 10.6023/cjoc201701043
The first rhodium-catalyzed stereospecific intermolecular [3+2] cycloaddition reaction of vinylaziridines with ynamides was realized. The salient features of the transformation include broad substrate scope, mild reaction condition, and simple operation. Moreover, the chirality of vinylaziridines can be completely transferred to the cycloadducts, representing an atom-economic and enantiospecific protocol for the construction of valuable 2-amino pyrroline derivatives.
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