镍催化格氏试剂与二芳基乙炔偶联反应制备四取代萘
收稿日期: 2016-12-24
修回日期: 2017-02-21
网络出版日期: 2017-03-14
基金资助
湖南省科技重大专项基金（No.2014FJ1010）资助项目.
Nickel-Catalyzed Coupling of Grignard Reagents and Diaryl Acetylenes for Synthesis of Tetra-substituted Naphthalenes
Received date: 2016-12-24
Revised date: 2017-02-21
Online published: 2017-03-14
Supported by
Project supported by the Hunan Provincal Science and Technology Major Projects (No.2014FJ1010).
陈锦杨 , 吴小波 , 易荣楠 , 许新华 . 镍催化格氏试剂与二芳基乙炔偶联反应制备四取代萘[J]. 有机化学, 2017 , 37(7) : 1850 -1854 . DOI: 10.6023/cjoc201612057
A novel approach for the synthesis of tetra-substituted naphthalenes is demonstrated through the ligand-free coupling of a wide range of alkynes with Grignard reagents catalyzed by NiCl2, avoiding the use of special ligands and expensive catalysts used in previous methods. Other outstanding features include mild reaction conditions, good yields and wide functional group tolerance. The protocol provides an efficient method for the synthesis of highly substituted naphthalenes.
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