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2017 , Vol. 37 >Issue 5: 1160 - 1164

DOI: https://doi.org/10.6023/cjoc201702036

研究通讯

铁催化烯基芳烃的氢芳基化、甲基芳基化和二芳基化制备非对称1，1-二芳基烷烃的反应（英文）

  • Kaki Raveendra Babu ,
  • 陈绍维 ,
  • 李亚军 ,
  • 鲍红丽
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  • a 福州大学化学化工学院 福州 350108;
    b 中国科学院福建物质结构研究所 煤制乙二醇及相关技术重点实验室 福州 350002

收稿日期: 2017-02-25

  修回日期: 2017-03-25

  网络出版日期: 2017-03-31

基金资助

国家自然科学基金（Nos.21402200，21502191，21672213，21232001），中国科学院战略先导科技专项（No.XDB20000000）资助项目.

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Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes

  • Babu Kaki Raveendra ,
  • Chen Shaowei ,
  • Li Yajun ,
  • Bao Hongli
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  • a College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108;
    b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou 350002

Received date: 2017-02-25

  Revised date: 2017-03-25

  Online published: 2017-03-31

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21402200, 21502191, 21672213, 21232001), the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB20000000).

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摘要

报道了一种新型的铁催化的烯基芳烃的氢芳基化、甲基芳基化和双芳基化的反应.富电子的苯甲醚以及1，3，5-三甲氧基苯在温和条件下和烯基芳烃反应得到非对称的1，1-二芳基烷烃.其中，在氢芳基化反应中，苯甲酰基过氧化物被用作氧化剂；在甲基芳基化和双芳基化反应中，叔丁基过氧酯是氧化剂.

关键词： 氢芳基化; 甲基芳基化; 双芳基化; 烯基芳烃; 1; 1-二芳基烷烃

本文引用格式

Kaki Raveendra Babu , 陈绍维 , 李亚军 , 鲍红丽 . 铁催化烯基芳烃的氢芳基化、甲基芳基化和二芳基化制备非对称1，1-二芳基烷烃的反应（英文）[J]. 有机化学, 2017 , 37(5) : 1160 -1164 . DOI: 10.6023/cjoc201702036

Abstract

A novel iron catalyzed hydroarylation, methylarylation, and diarylation of styrenes to form unsymmetrical 1,1-diarylalkanes with electron rich anisole and 1,3,5-trimethoxybenzene under mild conditions have been developed. Benzoyl peroxide is used as an oxidant for hydroarylation, whereas in the case of methylarylation and diarylation the oxidant tert-butyl peracetate is used.

Key words： hydroarylation; methylarylation; diarylation; vinylarenes; 1,1-diarylalkanes

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