4，4'-取代-2，2'-联吡啶钠和铕穴状化合物的合成和性质（英文）
收稿日期: 2017-02-03
修回日期: 2017-03-27
网络出版日期: 2017-04-01
基金资助
国家自然科学基金（No.21372171）资助项目.
Synthesis and Properties of Sodium and Europium(Ⅲ) Cryptates Incorporating the 4,4'-Substituted-2,2'-bipyridine Units
Received date: 2017-02-03
Revised date: 2017-03-27
Online published: 2017-04-01
Supported by
Project supported by the National Natural Science Foundation of China (No. 21372171).
报道了由芳香醛合成4，4'，6，6'-取代-2，2'-联吡啶化合物的方法，合成了一系列钠穴状化合物以及两个铕穴状化合物[Eu⊂bpy·bpy·bpy]·2Cl·Br（bpy=6，6'-二亚甲基-2，2'-联吡啶-4，4'-二甲酯）（23）和[Eu⊂bpy1·bpy1·bpy2]·2Cl·Br（bpy1=6，6'-二亚甲基-2，2'-联吡啶-4，4'-二甲酸，bpy2=6，6'-二亚甲基-2，2'-联吡啶-4，4'-二甲酰乙二胺）（24）.目标化合物均经过1H NMR、13C NMR和高分辨质谱（HRMS）表征.X射线单晶衍射（XRD）和HRMS鉴定了铕穴状化合物23的结构.对23的荧光光谱（PL）、荧光衰减曲线和绝对量子产率（η）的研究结果表明，23能够有效地被近紫外光激发，显示荧光寿命（τ）为0.32 ms，η为70%的亮红色荧光，表明23是一种在发光和照明显示之中有着潜在应用的荧光材料.
陈素芳 , 洪玉标 , 刘元忠 , 薛明强 , 郑煜 , 沈琪 . 4，4'-取代-2，2'-联吡啶钠和铕穴状化合物的合成和性质（英文）[J]. 有机化学, 2017 , 37(5) : 1198 -1204 . DOI: 10.6023/cjoc201702004
A general strategy for the syntheses of 4,4',6,6'-substituted-2,2'-bipyridines starting from aromatic aldehyde is described. A series of sodium cryptates and two europium cryptates [Eu⊂bpy·bpy·bpy]·2Cl·Br (bpy=6,6'-dimethylene-2,2'-bipyridine-4,4'-dimethylester) (23) and [Eu⊂bpy1·bpy1·bpy2]·2Cl·Br (bpy1=6,6'-dimethylene-2,2'-bipyridine-4,4'-dicarboxylic acid, bpy2=6,6'-dimethylene-2,2'-bipyridine-4,4'-diformylethylenediamine) (24), were synthesized from these compounds. Sodium cryptates have been confirmed by 1H NMR, 13C NMR and high resolution mass spectrum (HRMS). The structure of europium cryptate 23 was confirmed by X-ray diffraction (XRD) and HRMS. The photoluminescence (PL) spectra, decay curve and the absolute quantum efficiency (η) of 23 are presented. 23 can be efficiently excited by near-UV light and presents a bright red luminescence with the lifetime (τ) of 0.32 ms and the η of 70%. It is suggested that 23 is expected to be a potential efficient phosphor for lighting and display.
Key words： cryptates; spectroscopy; macrocyclic compounds; phosphor; crystal structure
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