腐殖酸催化合成1,4-二氢吡啶类化合物
收稿日期: 2016-12-22
修回日期: 2017-03-13
网络出版日期: 2017-04-10
基金资助
安徽省先进功能复合材料协同创新中心开放基金（No.20160804）资助项目.
Synthesis of 1,4-Dihydropyridine Compounds Catalyzed by Humic Acid
Received date: 2016-12-22
Revised date: 2017-03-13
Online published: 2017-04-10
Supported by
Project supported by the Open Fund of Anhui Collaborative Innovation Center for Advanced Function Composites (No.20160804).
魏振中 , 李江飞 , 王泽云 , 李品华 , 王永秋 . 腐殖酸催化合成1,4-二氢吡啶类化合物[J]. 有机化学, 2017 , 37(7) : 1835 -1838 . DOI: 10.6023/cjoc201612055
A novel, efficient and straightforward method to synthesize 1,4-dihydropyridine compounds with excellent yields is reported through Hantzsch reaction of aldehydes, ammonium acetate and ethyl acetoacetate or methyl acetoacetate using humic acid as the catalyst. This method has high yield and less pollution. The catalyst is easy to recycle and environment friendly.
Key words： humic acid; catalysis; 1,4-dihydropyridine
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