手性多齿胺膦配体/铁簇合物催化酮的不对称转移氢化反应
收稿日期: 2017-02-27
修回日期: 2017-04-01
网络出版日期: 2017-04-13
基金资助
国家自然科学基金（Nos.21173176，21673190）、中央高校基本科研业务费专项资金（No.20720150040）资助项目.
Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Chiral Multidentate Aminophosphine Ligands/Iron Cluster
Received date: 2017-02-27
Revised date: 2017-04-01
Online published: 2017-04-13
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21173176, 21673190) and the Fundamental Research Funds for the Central Universities (No. 20720150040).
吴访 , 张文景 , 安冬丽 , 李岩云 , 高景星 . 手性多齿胺膦配体/铁簇合物催化酮的不对称转移氢化反应[J]. 有机化学, 2017 , 37(5) : 1295 -1299 . DOI: 10.6023/cjoc201702043
As one of the most abundant metals on earth, iron is cheap and low toxicity. Herein we reported the asymmetric transfer hydrogenation of (ATH) ketones catalyzed by the system generated in situ from chiral multidentate aminophosphine ligand (R,R,R,R)-PN4H6 and Fe3(CO)12. The effects of temperature and additive on the ATH of propiophenone were examined. After optimizing the reaction conditions, we applied the catalytic system to the ATH of various aromatic ketones, obtaining the corresponding optical active alcohols with high enantioselectivities (up to 96% ee).
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