N-溴代丁二酰亚胺催化水杨醛与麦氏酸反应合成香豆素-3-羧酸
收稿日期: 2017-01-05
修回日期: 2017-03-21
网络出版日期: 2017-04-18
基金资助
国家自然科学基金（No.21403100）和辽宁省博士启动基金（No.20141100）资助项目.
N-Bromosuccinimide Mediated the Reaction of 2-Hydroxyaryl Aldehydes with Meldrum's Acid for Synthesis of Coumarin-3-carboxylic Acids
Received date: 2017-01-05
Revised date: 2017-03-21
Online published: 2017-04-18
Supported by
Project supported by the National Natural Science Foundation of China (No. 21403100) and the Doctoral Scientific Research Foundation of Liaoning Province (No. 20141100).
阮鸿力, 张婧圆, 孙赛, 杨颖, 朱小磊, 吕成伟 . N-溴代丁二酰亚胺催化水杨醛与麦氏酸反应合成香豆素-3-羧酸[J]. 有机化学, 2017 , 37(8) : 2139 -2144 . DOI: 10.6023/cjoc201701003
A N-bromosuccinimide (NBS) promoted procedure for the synthesis of coumarin-3-carboxylic acids via Knoevenagel-intramolecular cyclization cascade reaction of Meldrum's acid with various 2-hydroxyarylaldehydes has been developed. Using the mixture of water and ethanol as solvent, employing inexpensive NBS as the catalyst, and reacted at room temperature are found to highly applicable to get a satisfactory outcome. This approach expands the method for the preparation of coumarin-3-carboxylic acids and also provides other features such as mild reaction conditions, tolerant the substrates with diverse functional groups, simple workup procedure and easy isolation.
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