含嘧啶环的新型棒-线状N^C^N型二价铂配合物的合成及其自组装和荧光性能的表征
收稿日期: 2017-04-20
修回日期: 2017-06-13
网络出版日期: 2017-06-16
基金资助
上海市科委科技创新行动计划基础研究（No.16JC1401900）资助项目.
Synthesis,Self-Assemble and Fluorescence of Pyrimidine-Contained Novel Rod-Coil Structured N^C^N-Type Divalent Platium Complexes
Received date: 2017-04-20
Revised date: 2017-06-13
Online published: 2017-06-16
Supported by
Project supported by the Science and Technology Commission of Shanghai Municipality (No.16JC1401900).
杨蕾 , 胡杰娜 , 曾旺 , 吴洋 , 李贤英 , 张灯青 , 金武松 . 含嘧啶环的新型棒-线状N^C^N型二价铂配合物的合成及其自组装和荧光性能的表征[J]. 有机化学, 2017 , 37(10) : 2647 -2654 . DOI: 10.6023/cjoc201704035
Pyrimidine-contained novel rod-coil shaped N^C^N-type tridentate ligand 1 and its platinum(Ⅱ) complexe 1-Pt were synthesized, and their structures were characterized by NMR spectroscopy and MALDI-TOF mass spectrometry. The self-assembly and optical properties of 1-Pt were investigated with FE-SEM, UV-Vis and fluorescence spectroscopies. The result indicated that the unique rod-coil structure of 1-Pt enhanced intermolecular π-π stacking and showed excellent self-assembly performance in organic solvents which allowing for modulation of luminescence.
Key words： pyrimidine; rod-coil structure; platinum(Ⅱ) complex; self-assembly; fluorescence
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