水/离子液体中无负载PdCl2循环催化Suzuki-Miyaura和Mizoroki-Heck反应的研究
收稿日期: 2017-06-14
修回日期: 2017-07-11
网络出版日期: 2017-08-09
基金资助
国家自然科学基金（Nos.21563015，51363009）和江西省自然科学基金（No.20151BAB203010）资助项目.
Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media
Received date: 2017-06-14
Revised date: 2017-07-11
Online published: 2017-08-09
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21563015, 51363009) and the Natural Science Foundation of Jiangxi Province (No. 20151BAB203010).
唐伯孝 , 方小牛 , 匡仁云 , 蔡金华 , 吴建宏 . 水/离子液体中无负载PdCl2循环催化Suzuki-Miyaura和Mizoroki-Heck反应的研究[J]. 有机化学, 2017 , 37(11) : 2956 -2961 . DOI: 10.6023/cjoc201706016
Efficient and unsupported protocols were developed for PdCl2-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions using water/ionic liquid systems to afford the cross-coupling products with excellent yields. It is noteworthy that the PdCl2/K2CO3/water/ionic liquid systems can be recovered and used for 3~5 cycles directly. The results suggest that the unsupported and recyclable systems can be extended to the other realm of C-C bond formation.
Key words： carrier-free; recyclability; water/ionic liquid; coupling reaction
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