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2018 , Vol. 38 >Issue 1: 277 - 280

DOI: https://doi.org/10.6023/cjoc201707023

研究简报

α-亚胺基磷杂二茂铁的合成、结构及配位化学研究

  • 郝延蔚 ,
  • 田荣强 ,
  • 吴迪 ,
  • 段征 ,
  • Mathey Franç ,
  • ois
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  • a 郑州大学化学与分子工程学院 国际磷化学实验室 河南省有机磷功能分子国际联合实验室 郑州 450001;
    b 开封大学功能材料研究中心 河南省先进碳化硅材料重点实验室 开封 475001

收稿日期: 2017-07-21

  修回日期: 2017-09-09

  网络出版日期: 2017-09-15

基金资助

国家自然科学基金（Nos.21302174，21672193，21272218）、郑州大学优秀青年发展基金（No.1621316006）和郑州大学资助项目.

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Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene

  • Hao Yanwei ,
  • Tian Rongqiang ,
  • Wu Di ,
  • Duan Zheng ,
  • Mathey Franç ,
  • ois
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  • a International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001;
    b Key Laboratory for Advanced Silicon Carbide Materials, Research Center of Functional Materials, Kaifeng University, Kaifeng 475001

Received date: 2017-07-21

  Revised date: 2017-09-09

  Online published: 2017-09-15

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21302174, 21672193, 21272218), the Young Talent Research Fund of Zhengzhou University (No. 1621316006) and the Zhengzhou University of China.

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摘要

3，4-二甲基-1-苯基磷杂环戊二烯通过两次[1，5]σ-迁移在α-位分别引入苯基和亚胺基得到α-亚胺基磷杂环戊二烯负离子1，1和[Cp*FeCl]n反应得到新的P，N双齿配体α-亚胺基磷杂二茂铁2.2可以和Mo和Rh等形成配合物，其中2及其Mo配合物的结构由X射线单晶衍射确定.

关键词： 磷杂二茂铁; 亚胺; 配位化学

本文引用格式

郝延蔚 , 田荣强 , 吴迪 , 段征 , Mathey Franç , ois . α-亚胺基磷杂二茂铁的合成、结构及配位化学研究[J]. 有机化学, 2018 , 38(1) : 277 -280 . DOI: 10.6023/cjoc201707023

Abstract

An 2-iminophospholide 1 can be obtained via two [1,5] shifts by reaction of potassium tert-butoxide with 3,4-di- methyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp*FeCl]n affords a 2-iminophosphaferrocene 2 which behaves as a P,N chelating ligand toward Mo(CO)4 and Rh(CO)2]+. The X-ray crystal structures of 2 and its Mo complex have been recorded.

Key words： phosphaferrocene; imine; coordination chemistry

参考文献

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