卤代苯腈硫解反应规律的研究进展
收稿日期: 2017-07-03
修回日期: 2017-09-23
网络出版日期: 2017-10-20
基金资助
国家自然科学基金（No.21362019）、内蒙自然科学基金（No.2016MS0207）和中国科学院“西部之光”人才培养计划项目.
Research Progress for the Thiolysis Reaction of Halobenzonitrile
Received date: 2017-07-03
Revised date: 2017-09-23
Online published: 2017-10-20
Supported by
Project supported by the National Natural Science Foundation of China (No. 21362019), the Natural Science Foundation of Inner Mongolia (No. 2016MS0207) and the "Light of West China" Program of Chinese Academy of Sciences.
李闪闪 , 洪海龙 , 韩利民 , 张田苗 , 王云龙 , 竺宁 . 卤代苯腈硫解反应规律的研究进展[J]. 有机化学, 2018 , 38(2) : 304 -315 . DOI: 10.6023/cjoc201707002
Halobenzonitrile is an important raw material in the fields of medicine, pesticide and materials. Halobenzonitrile has a nitrile group and a halo group which all could react with nucleophile reagents. The law for the selective synthesis of halothiobenzamide or mercaptobenzonitrile from the reaction of halobenzonitrile and different sulfur source is summarized. It is found that the halothiobenzamide product could be synthesized under protonic acid condition from halobenzonitrile, while the mercaptobenzonitrile product would be formed under the alkaline conditions.
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