一种氟离子荧光传感器分子的合成及性能研究
收稿日期: 2017-11-30
修回日期: 2018-02-03
网络出版日期: 2018-03-29
基金资助
国家自然科学基金(No.21676075)资助项目.
Synthesis and Properties of a Fluoride Ion Fluorescence Chemosensor
Received date: 2017-11-30
Revised date: 2018-02-03
Online published: 2018-03-29
Supported by
Project supported by the National Natural Science Foundation of China (No. 21676075).
付怡 , 唐辉 , 刘泽 , 张万轩 , 任君 . 一种氟离子荧光传感器分子的合成及性能研究[J]. 有机化学, 2018 , 38(7) : 1806 -1810 . DOI: 10.6023/cjoc201711049
Fluoride ion is an anion with the high electronegativity and the smallest radius. It has important application in all aspects of daily life. In this paper, based on the cleavage of Si-O bond induced by fluoride ions, a novel derivative of perylene B which contains four silicon oxygen bond was designed and synthesized, and this fluorescent chemosensor could recognize F- with good selectivity and high sensitivity. The probe molecule had a fast response time for F- and the sensing procedure could be completed in about 1 min, and the detection limit of F- of the probe molecule B reached 3.5×10-8 mol·L-1.
Key words: perylene; siloxane bonds; fluorescence sensor; fluoride ion
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