无碱条件下铜催化的苄醇在水中的氧化反应
收稿日期: 2018-02-12
修回日期: 2018-04-13
网络出版日期: 2018-06-01
基金资助
四川省杰出青年基金（No.2017JQ0010）、国家高新技术部研发（No.2016ZX05053）、四川省教委重点基金（No.16CZ0008）、西南石油大学油气藏地质与开发国家重点实验室勘探项目基金（No.G201601）资助项目.
Copper-Catalyzed Aerobic Oxidation Reaction of Benzyl Alcohol in Water under Base-Free Condition
Received date: 2018-02-12
Revised date: 2018-04-13
Online published: 2018-06-01
Supported by
Project supported by the Sichuan Youth Science & Technology Foundation (No. 2017JQ0010), the National High Technology Research & Development Program (No. 2016ZX05053), the Key Fund Project of Educational Commission of Sichuan Province (No. 16CZ0008), the Explorative Project Fund of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University) (No. G201601).
杨小江 , 毛金成 , 张恒 , 张阳 , 毛金桦 . 无碱条件下铜催化的苄醇在水中的氧化反应[J]. 有机化学, 2018 , 38(10) : 2780 -2783 . DOI: 10.6023/cjoc201802018
A green and very mild method for the oxidation of benzyl alcohols to aromatic aldehydes with excellent conversions has been developed. The reaction could be carried out directly in air at room temperature and was catalyzed by bis (8-quinolinolato) copper (Ⅱ) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) as co-catalysts. The methodology provided a practical approach for the synthesis of aromatic aldehydes, which has the advantages of environment-friendly, simple workup and high yields.
Key words： benzyl alcohol; aromatic aldehyde; copper; TEMPO; aerobic oxidation
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