铜催化醛肟脱水/贝克曼重排选择性可切换反应
收稿日期: 2018-05-22
修回日期: 2018-06-11
网络出版日期: 2018-06-15
基金资助
国家自然科学基金（No.21202141）、江苏省高校优势学科项目及广陵学院自然科学基金（No.ZKZD17005）资助项目.
Copper-Catalyzed Selectivity-Switchable Dehydration/Beckmann Rearrangement Reactions of Aldoxime
Received date: 2018-05-22
Revised date: 2018-06-11
Online published: 2018-06-15
Supported by
Project supported by the National Natural Science Foundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and the Natural Science Foundation of Guangling College (No. ZKZD17005).
范昕 , 易容 , 王芳 , 张旭 , 徐清 , 俞磊 . 铜催化醛肟脱水/贝克曼重排选择性可切换反应[J]. 有机化学, 2018 , 38(10) : 2736 -2740 . DOI: 10.6023/cjoc201805044
It was found that, copper as a cheap metal, could well catalyze the dehydration reaction of aldoximes to organonitriles in nitrile solvent by using MnO2 as the co-catalyst and PPh3 as the ligand. In contrast, instead of organonitriles, the Cu-catalyzed reactions of the aldoximes in water led to amides, which were the products of the Beckmann rearrangements. These interesting selectivity-switchable reactions afford easy accesses to the related useful organic compounds and may be of both academic and practical values.
Key words： aldoxime; dehydration; Beckmann rearrangement; nitrile; amide
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