双齿N基配体锇配合物的合成及其在催化氨硼烷释氢中的应用
收稿日期: 2018-05-28
修回日期: 2018-07-10
网络出版日期: 2018-08-14
基金资助
国家自然科学基金（Nos.21501048，21503070，21571052，21771057）及河南省重点科技攻关（No.182102210377）资助项目.
Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane
Received date: 2018-05-28
Revised date: 2018-07-10
Online published: 2018-08-14
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21501048, 21503070, 21571052, 21771057) and the Key Science and Technology Project of Henan Province (No.182102210377).
赵茜怡 , 梁媛 , 徐霆 , 窦婷 , 张絜 , 陈学年 . 双齿N基配体锇配合物的合成及其在催化氨硼烷释氢中的应用[J]. 有机化学, 2018 , 38(12) : 3286 -3295 . DOI: 10.6023/cjoc201805050
Reactions of OsCl2(PPh3)3 (1) with bidentate nitrogen-based ligands at room temperature led to the formation of complexes OsCl2(PPh3)2(diamine) (2~6) and OsCl2(PPh3)2(Phen*) (7~11). Complexes 2~11 showed high activity in the catalytic dehydrogenation of ammonia borane at 60℃, in THF/DME (V:V=1:1.6) solution with the catalyst loading of 5 mol%. Among all the catalysts, compound 4 demonstrated the highest catalytic activity, which represents the most efficient osmium catalyst in catalytic dehydrogenation of ammonia borane until now.
Key words： osmium; complex; synthesis; catalytic dehydrogenation; ammonia borane
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