环糊精/氨基粘土超分子水凝胶的构筑及其I3-/I2吸附性能
收稿日期: 2018-07-29
修回日期: 2018-09-17
网络出版日期: 2018-09-26
基金资助
国家自然科学基金（Nos.21432004，21672113，21772099，21861132001，91527301）资助项目.
Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I3-/I2 Adsorption Property
Received date: 2018-07-29
Revised date: 2018-09-17
Online published: 2018-09-26
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21432004, 21672113, 21772099, 21861132001, 91527301).
牛杰 , 陈湧 , 刘育 . 环糊精/氨基粘土超分子水凝胶的构筑及其I3-/I2吸附性能[J]. 有机化学, 2019 , 39(1) : 151 -156 . DOI: 10.6023/cjoc201807054
Aminoclay (AC), as a kind of layered silicates with positive charges, shows high dispersity in water and has been widely applied in the fabrication of intelligent hybrid hydrogel. Herein, heptakis-[6-deoxy-6-(2-sulfanylethanesulfonic acid)]-β-cyclodextrin (SCD), a kind of negatively charged cyclodextrin, was employed to construct the supramolecular hydrogel with aminoclay through the static electronic interactions, and the resultant SCD-AC hydrogel was fully characterized by means of X-ray powder diffraction (XRD), scanning electronic microscopy (SEM), fourier transform infrared spectroscopy (FT-IR), zeta potential, rheological test, etc. Significantly, the SCD-AC hydrogel can efficiently absorb not only I3- ion in aqueous solution but also I2 molecule in organic solvent, giving a high adsorption capacity up to 90% with 10 min.
Key words： supramolecular hydrogel; cyclodextrin; aminoclay; iodine; adsorption
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