苯基三氟硼酸钾催化的硅烷还原羰基化合物成醇反应
收稿日期: 2018-10-11
修回日期: 2018-12-12
网络出版日期: 2019-01-18
基金资助
精细化工国家重点实验室（盘锦）（No.JH2014009）和重点大学基础研究基金资助项目.
Potassium Phenyltrifluoroborate-Catalyzed Reduction of Aldehydes and Ketones into Alcohol with Silanes
Received date: 2018-10-11
Revised date: 2018-12-12
Online published: 2019-01-18
Supported by
Project supported by the State Key Laboratory of Fine Chemicals (Panjin) (No. JH2014009) and the Fundamental Research Funds for the Central Universities.
刘建辉 , 王星旸 . 苯基三氟硼酸钾催化的硅烷还原羰基化合物成醇反应[J]. 有机化学, 2019 , 39(5) : 1411 -1416 . DOI: 10.6023/cjoc201810010
The selective reduction of carbonyl group with organosilane as reducing agent was studied with methanol as a solvent under the action of 2.5 mol% C6H5BF3K and 2.2 epuiv. (EtO)3SiH. The target products were obtained in medium to high yield. This method shows good selectivity and provides a new method for carbonyl reduction.
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