三氯异氰尿酸促进下腙的氯化反应研究
收稿日期: 2018-11-30
修回日期: 2019-01-17
网络出版日期: 2019-01-31
基金资助
国家自然科学基金（No.21662030）资助项目.
Study on the Chlorination Reaction of Hydrazones by Using of Trichloroisocyanuric Acid as Chloride Source
Received date: 2018-11-30
Revised date: 2019-01-17
Online published: 2019-01-31
Supported by
Project supported by the National Natural Science Foundation of China (No. 21662030).
宗吴中 , 胡雨来 , 王小平 , 刘佳欣 , 黄丹凤 , 王克虎 . 三氯异氰尿酸促进下腙的氯化反应研究[J]. 有机化学, 2019 , 39(5) : 1396 -1403 . DOI: 10.6023/cjoc201811039
The chlorination reaction of hydrazones with N-aryltrifluoroacetohydrazones by using trichloroisocyanuric acid as chlorine source was investigated, and a series of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides were obtained in high yields. This method had advatages of easy operation, short reaction time, mild conditions and the use of stable and cheap chlorine source, which provides an efficiant method for the synthesis of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides.
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