6-甲氧基喹唑啉酮-吡啶二氟硼染料的合成及发光性能研究
收稿日期: 2019-01-03
修回日期: 2019-02-03
网络出版日期: 2019-02-22
基金资助
国家自然科学基金（Nos.21606116，51873160）、江西省自然科学基金（No.20161BAB213070）和江西省教育厅科技（No.GJJ170176）资助项目.
Synthesis and Luminescent Properties of 6-Methoxy-quinazolinone-pyridine Difluoroboron Dyes
Received date: 2019-01-03
Revised date: 2019-02-03
Online published: 2019-02-22
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21606116, 51873160), the Natural Science Foundations of Jiangxi Province (No. 20161BAB213070) and the Department of Education of Jiangxi Province (No. GJJ170176).
周佳 , 刘璐 , 钟成 , 傅杨 , 宋智彬 , 彭以元 . 6-甲氧基喹唑啉酮-吡啶二氟硼染料的合成及发光性能研究[J]. 有机化学, 2019 , 39(5) : 1444 -1449 . DOI: 10.6023/cjoc201901003
6-Methoxyquinazolinone-pyridine difluoroboron dyes (BODIQPys) have been synthesized in two simple steps with 2-amino-5-methoxybenzamide and 2-methylpyridines as starting materials. These quinazolinone-based difluoroboron (BF2) complexes exhibited highly efficient green luminescence and remarkable fluorescence in the solid-state with very large Stokes shift (Δλ up to 220 nm in MeCN). The introduction of methoxy group at 6-position of BODIQPy caused the red-shifted emission by the enhancement of charge transfer property. The introduction of halogen atom at pyridine moiety of BODIQPy can tune the LUMO levels in regularity while their HOMO levels remain intact.
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