高价碘试剂的有机电化学合成及应用研究进展
收稿日期: 2019-02-11
修回日期: 2019-03-10
网络出版日期: 2019-04-09
基金资助
甘肃省高等学校科学研究（No.2018B-091）和兰州石化职业技术学院教科研（No.JY2018-25）资助项目.
Recent Advances in Organic Electrochemical Synthesis and Application of Hypervalent Iodine Reagents
Received date: 2019-02-11
Revised date: 2019-03-10
Online published: 2019-04-09
Supported by
Project supported by the Scientific Research Projects of Colleges and Universities in Gansu Province (No. 2018B-091) and the Teaching and Scientific Research Project of Lanzhou Petrochemical Poly Technic (No. JY2018-25).
张怀远 , 唐蓉萍 , 石星丽 , 颉林 , 伍家卫 . 高价碘试剂的有机电化学合成及应用研究进展[J]. 有机化学, 2019 , 39(7) : 1837 -1845 . DOI: 10.6023/cjoc201902006
Anodic oxidation of aryl iodine compouds is a green and efficient method for the synthesis of hypervalent iodine reagents. This method replaces chemical reagents with electric current, avoiding the use of expensive and handle difficult oxidants such as m-CPBA, H2O2, oxone, selectfluor etc. Electrochemically generated hypervalent iodine reagents can not only promote fluorination, oxidative cyclization, but also be successfully applied in the total synthesis of natural products. In addition, recyclable aryl iodine mediator can be used to indirect anodic fluorination and easily separated from products. The organic electrochemical synthesis of hypervalent iodine reagents and their applications in various chemical transformations are reviewed.
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