NaBH4/I2介导的醇的碘化反应
收稿日期: 2019-03-20
修回日期: 2019-04-17
网络出版日期: 2019-04-26
基金资助
国家自然科学基金（Nos.21871163，91645120）资助项目.
NaBH4/I2-Mediated Efficient Iodination of Alcohols
Received date: 2019-03-20
Revised date: 2019-04-17
Online published: 2019-04-26
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21871163, 91645120).
樊正宁 , 张博 , 席婵娟 . NaBH4/I2介导的醇的碘化反应[J]. 有机化学, 2019 , 39(8) : 2333 -2337 . DOI: 10.6023/cjoc201903036
A simple, mild, and high yielding procedure for the iodination of alcohols using a combination of NaBH4 and I2 is described. The effectiveness of the protocol is achieved with benzylic alcohols and primary alkylic alcohols whereas allylic and secondary alcohols are found to be unreactive.
Key words： alcohol; iodide; sodium borohydride; iodination
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