咔唑基高价碘试剂参与的活化芳烃直接咔唑化反应研究
收稿日期: 2019-05-28
修回日期: 2019-07-12
网络出版日期: 2019-07-17
基金资助
国家重点研发计划（No.2016YFB0401400）、国家自然科学基金（Nos.21302139，21672120，21871158）和霍英东青年教师基金（No.151014）资助项目.
Carbazolation Study of Active Arenes with Carbazole-Containing Hypervalent Iodine(III) Reagents
Received date: 2019-05-28
Revised date: 2019-07-12
Online published: 2019-07-17
Supported by
Project supported by the National Key Research and Development Program of China (No. 2016YFB0401400), the National Natural Science Foundation of China (Nos. 21302139, 21672120, 21871158) and the Fok Ying Tong Education Foundation of China (No. 151014).
兰天磊 , 张越 , 刘伟 , 席婵娟 , 陈超 . 咔唑基高价碘试剂参与的活化芳烃直接咔唑化反应研究[J]. 有机化学, 2019 , 39(8) : 2166 -2174 . DOI: 10.6023/cjoc201905050
Carbazole and its derivatives are widely used in the field of medicine and photoelectric materials. A kind of stable cyclic hypervalent iodine reagents containing carbazole group was developed, which belong to benziodoxole compounds. In the presence of Cu(I) catalyst, these reagents reacted with aromatic substrates to give N-aryl carbazole derivatives. The reaction conditions are mild and suitable for a variety of electron-rich arenes. And a radical mechanism was proposed.
Key words： carbazole; hypervalent iodine reagent; N-arylation; copper-catalysis
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