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2020 , Vol. 40 >Issue 2: 339 - 350

DOI: https://doi.org/10.6023/cjoc201909024

综述与进展

光催化有机物偶联/芳构化放氢反应研究进展

  • 陈锋 ,
  • 陈浩 ,
  • 吴庆安 ,
  • 罗书平
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  • 浙江工业大学化学工程学院 绿色化学合成技术国家重点实验室培育基地 杭州 310014

收稿日期: 2019-09-16

  修回日期: 2019-10-18

  网络出版日期: 2019-11-01

基金资助

国家自然科学基金（No.21376222）和浙江省自然科学基金（No.LY18B060011）资助项目.

收起

Progress on the Photocatalytic Organic Hydrogen-Evolution Coupling/Aromatization Reaction

  • Chen Feng ,
  • Chen Hao ,
  • Wu Qing'an ,
  • Luo Shuping
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  • State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014

Received date: 2019-09-16

  Revised date: 2019-10-18

  Online published: 2019-11-01

Supported by

Project supported by the National Natural Science Foundation of China (No. 21376222) and the Natural Science Foundation of Zhejiang Province (No. LY18B060011).

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摘要

光催化氧化还原反应具有绿色、高效、安全等优势，已经在有机化学中得到广泛关注.介绍了基于光催化的偶联/芳构化放氢反应，通过使用光催化剂/催化剂的双催化体系，可用于光催化有机碳-碳和碳-杂原子成键反应，且反应中氢气是唯一的副产物.强调了有机光氧化还原体系的构建与催化机理.

关键词： 光催化; 有机物放氢反应; 偶联反应; 芳构化反应

本文引用格式

陈锋 , 陈浩 , 吴庆安 , 罗书平 . 光催化有机物偶联/芳构化放氢反应研究进展[J]. 有机化学, 2020 , 40(2) : 339 -350 . DOI: 10.6023/cjoc201909024

Abstract

The photocatalytic redox reactions have been widely concerned in organic chemistry due to their green, efficiency and safety. In this review, the cross-coupling/aromatization reactions are described based on photocatalytic organic hydrogen-evolution, which can be used to build organic carbon-carbon and carbon-heteroatom bonds by using a photocatalyst/catalyst dual catalytic system. Hydrogen is the only by-product in these reactions. The system and catalytic mechanisms of organic photocatalytic redox reaction are highlighted.

Key words： photocatalysis; organic hydrogen-evolution reaction; coupling reaction; aromatization reaction

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