研究简报

双官能膦配体-金(I)高效催化合成1,5-苯并二氮(艹卓)

  • 郑康河 ,
  • 周丙伟 ,
  • 金红卫 ,
  • 刘运奎
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  • 浙江工业大学化学工程学院 绿色化学与技术国家重点实验室培育基地 杭州 310014

收稿日期: 2020-03-09

  修回日期: 2020-05-28

  网络出版日期: 2020-06-10

基金资助

国家自然科学基金(Nos.21772176,21372201)和浙江省自然科学基金(No.LY20B020013)资助项目.

Bifunctional Phosphine Ligand-Enabled Gold(I)-Catalyzed Efficient Synthesis of 1,5-Benzodiazepines

  • Zheng Kanghe ,
  • Zhou Bingwei ,
  • Jin Hongwei ,
  • Liu Yunkui
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  • State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014

Received date: 2020-03-09

  Revised date: 2020-05-28

  Online published: 2020-06-10

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21772176, 21372201), and the Natural Science Foundation of Zhejiang Province (No. LY20B020013).

摘要

在室温条件下,使用双官能膦-金(I)催化剂催化邻苯二胺与炔烃进行亲核加成/环化反应,一步合成1,5-苯并二氮(艹卓)类化合物.该反应具有原子经济性高、原料简单易得、操作便捷及反应温和等优点.

本文引用格式

郑康河 , 周丙伟 , 金红卫 , 刘运奎 . 双官能膦配体-金(I)高效催化合成1,5-苯并二氮(艹卓)[J]. 有机化学, 2020 , 40(8) : 2520 -2525 . DOI: 10.6023/cjoc202003024

Abstract

At room temperature, a bifunctional phosphine-gold(I) catalyst was used to catalyze the nucleophilic addition/cyclization reaction of o-phenylenediamines with alkynes to generate 1,5-benzodiazepines in one step. The reaction has the advantages of high atomic-economy, simple raw materials, convenient operation and mild reaction conditions.

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