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2020 , Vol. 40 >Issue 10: 3426 - 3430

DOI: https://doi.org/10.6023/cjoc202005022

研究论文

芳基硼酸和氟仿衍生三氟甲基银的氧化偶联反应

  • 欧阳瑶 ,
  • 徐修华 ,
  • 卿凤翎
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  • 中国科学院上海有机化学研究所 分子合成卓越中心 有机氟化学重点实验室 上海 200032

收稿日期: 2020-05-09

  修回日期: 2020-06-03

  网络出版日期: 2020-06-10

基金资助

国家自然科学基金（Nos.21421002，21991211）和中国科学院战略先导研究计划（No.XDB20000000）资助项目.

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Oxidative Coupling Reactions of Arylboronic Acids and Fluoroform-Derived AgCF3

  • Ouyang Yao ,
  • Xu Xiuhua ,
  • Qing Fengling
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  • Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2020-05-09

  Revised date: 2020-06-03

  Online published: 2020-06-10

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21421002, 21991211) and the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB20000000).

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摘要

以K2S2O8为氧化剂，芳基硼酸与氟仿衍生的AgCF3发生氧化偶联反应生成三氟甲基取代的芳烃及杂芳烃.该反应为构建Caryl—CF3键提供了新方法.

关键词： 氧化三氟甲基化反应; 硼酸; 氟仿; 三氟甲基银

本文引用格式

欧阳瑶 , 徐修华 , 卿凤翎 . 芳基硼酸和氟仿衍生三氟甲基银的氧化偶联反应[J]. 有机化学, 2020 , 40(10) : 3426 -3430 . DOI: 10.6023/cjoc202005022

Abstract

A silver-mediated oxidative coupling reaction of arylboronic acids with fluoroform-derived AgCF3 using K2S2O8 as oxidant was developed. This reaction provides a new route to trifluoromethylated arenes.

Key words： oxidative trifluoromethylation; arylboronic acids; fluoroform; trifluoromethyl silver

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