一种硫醚氧化为砜的绿色合成方法
收稿日期: 2020-07-09
修回日期: 2020-07-30
网络出版日期: 2020-08-27
基金资助
国家自然科学基金(21672151)
A Green Method for the Synthesis of Sulfones from Thioethers
Received date: 2020-07-09
Revised date: 2020-07-30
Online published: 2020-08-27
Supported by
the National Natural Science Foundation of China(21672151)
硫醚在Selectfluor TM的作用下, 以水作为氧源得到相应砜类化合物, 最高收率可达99%. 在重氧水标记下, 得到 18O标记的甲基苯基砜产物. 本方法绿色环保, 条件温和, 并可放大至克量级规模.
关键词： 硫醚; SelecetfluorTM; 水; 砜类化合物
方向 , 王旺 , 杨雪艳 , 吴范宏 . 一种硫醚氧化为砜的绿色合成方法[J]. 有机化学, 2021 , 41(1) : 412 -417 . DOI: 10.6023/cjoc202007028
With water as oxygen source, a method for the synthesis of sulfones from thioethers under the action of Selecetfluor TM was designed. The yield can reach 99%. The 18O-labeled methylphenylsulfone was prepared with H2 18O. The conditions of this green method are mild and can reach the grams scale.
Key words： thioethers; SelecetfluorTM; water; sulfone compound
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