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2021 , Vol. 41 >Issue 7: 2535 - 2570

DOI: https://doi.org/10.6023/cjoc202012013

综述与进展

基于电化学方法构建碳-氮键的最新研究进展

  • 蒙泽银 ,
  • 冯承涛 ,
  • 徐坤
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  • a 安徽理工大学化学工程学院 工业粉尘防控与职业安全健康教育部重点实验室 安徽淮南 232001
    b 北京工业大学环境与生命学部 北京 100124

收稿日期: 2020-12-06

  修回日期: 2021-02-23

  网络出版日期: 2021-03-09

基金资助

安徽省自然科学基金(2008085MB50); 北京市教委科研目(KM202110005006); 安徽理工大学研究生创新基金(2019CX2057)

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Recent Advances in the Electrochemical Formation of Carbon-Nitrogen Bonds

  • Zeyin Meng ,
  • Chengtao Feng ,
  • Kun Xu
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  • a Key Laboratory of Industrial Dust Control and Occupational Health, Ministry of Education, School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001
    b Faculty of Environment and Life, Beijing University of Technology, Beijing 100124
* Corresponding authors. E-mail: ;

Received date: 2020-12-06

  Revised date: 2021-02-23

  Online published: 2021-03-09

Supported by

Anhui Provincial Natural Science Foundation(2008085MB50); Beijing Education Committee Project(KM202110005006); Graduate Innovation Foundation of Anhui University of Science and Technology(2019CX2057)

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摘要

C—N键广泛存在于药物、天然产物以及功能材料中, 它的构建是有机合成化学的重要研究方向之一. 近年来,随着有机电化学的深入发展, 以有机电化学作为绿色合成手段, 高效地构建C—N键受到了合成化学家的广泛关注. 综述了从2015年至今有机电化学在构建C—N键领域所取得的研究进展, 对反应的条件和机理进行了总结, 并对该领域所面临的挑战及发展方向进行了展望与探讨, 希望能对从事该领域研究的学者以及相关人员提供参考.

关键词： 有机电化学; C—N键; 绿色化学

本文引用格式

蒙泽银 , 冯承涛 , 徐坤 . 基于电化学方法构建碳-氮键的最新研究进展[J]. 有机化学, 2021 , 41(7) : 2535 -2570 . DOI: 10.6023/cjoc202012013

Abstract

C—N bonds are widely existed in drugs, natural products, and functional materials. Thus, the construction of C—N bonds is one of the most important research areas in academia and industry. Recently, the renaissance in organic electrochemistry has promoted the electrochemical C—N bond formations to be a special branch of organic synthesis. The most recent advances in the electrochemical C—N bond formations since 2015 are summarized. The reaction mechanisms of these transformations are discussed, and the challenges and future directions of this important filed are included. We hope that this review can give references to the researchers, graduate students and other related people.

Key words： organic electrochemistry; carbon-nitrogen bond; green chemistry

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