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2021 , Vol. 41 >Issue 6: 2310 - 2318

DOI: https://doi.org/10.6023/cjoc202010010

研究论文

乳酸催化的酰胺与胺的氨解反应

  • 刘巨艳 ,
  • 赵聪颖
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  • 天津师范大学化学学院 天津市功能分子结构与性能重点实验室 天津 300387

收稿日期: 2020-10-09

  修回日期: 2020-12-28

  网络出版日期: 2021-03-25

基金资助

天津市自然科学基金(12JCZDJC34300); 大学生创业训练(201447)

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Lactic Acid-Catalyzed Transamidation Reactions of Carboxamides with Amines

  • Juyan Liu ,
  • Congying Zhao
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  • Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387
*Corresponding author.E-mail:

Received date: 2020-10-09

  Revised date: 2020-12-28

  Online published: 2021-03-25

Supported by

Natural Science Foundation of Tianjin City(12JCZDJC34300); College Studentsʼ Entrepreneurship Training Program(201447)

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摘要

发展了一种对环境友好的乳酸促进的酰胺与胺的氨解的新方法, 该方法能够成功合成一系列芳香、脂肪类酰胺和脲的衍生物. 该方法最显著的特征是催化剂廉价易得、无挥发性溶剂、底物转化率高及产物提纯操作简单.

关键词： 乳酸; 酰胺; 脲; 氨解

本文引用格式

刘巨艳 , 赵聪颖 . 乳酸催化的酰胺与胺的氨解反应[J]. 有机化学, 2021 , 41(6) : 2310 -2318 . DOI: 10.6023/cjoc202010010

Abstract

An environmentally benign protocol for the transamidation of carboxamides with amines using lactic acid as a green catalyst has been developed. The method has been successfully applied to the synthesis of a wide range of aromatic and aliphatic amides and ureas. The reaction has the advantages of the ready accessibility of the catalyst, solvent-free condition, efficient transformation and green processing.

Key words： lactic acid; carboxamide; urea; transamidation

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