铱催化的(杂)芳烃远端区域选择性C—H硼化反应的最新进展
收稿日期: 2021-03-10
修回日期: 2021-03-17
网络出版日期: 2021-03-25
基金资助
国家自然科学基金(91956116)
Recent Progress in Iridium-Catalyzed Remote Regioselective C—H Borylation of (Hetero)Arenes
Received date: 2021-03-10
Revised date: 2021-03-17
Online published: 2021-03-25
Supported by
National Natural Science Foundation of China(91956116)
邹晓亮 , 徐森苗 . 铱催化的(杂)芳烃远端区域选择性C—H硼化反应的最新进展[J]. 有机化学, 2021 , 41(7) : 2610 -2620 . DOI: 10.6023/cjoc202103020
(Hetero)Aryl boronic acids and their derivatives have been widely used in synthetic chemistry, material sciences, and drug discovery. Accordingly, the development of novel synthetic methods towards these structures has received a great deal of attention. In particular, Ir-catalyzed C—H borylation represents one of the most efficient methods. Due to the restriction of the reaction mechanism, regioselective controllable C—H borylation of Ir catalysis is a formidable challenge, and it is also an important development direction in this area. In this review, the recent progress in Ir-catalyzed remote selective C—H borylation of arenes is systematically discussed.
Key words： C—H activation; (hetero)aryl boronates; synthetic methods; borylation
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