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2021 , Vol. 41 >Issue 8: 3249 - 3255

DOI: https://doi.org/10.6023/cjoc202103015

研究论文

膦氧导向钯催化邻碳硼烷Heck类型的官能团化反应

  • 连凌翔 ,
  • 尹静怡 ,
  • 林彩霞 ,
  • 叶克印 ,
  • 袁耀锋
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  • 福州大学化学学院 福州 350108

收稿日期: 2021-03-06

  修回日期: 2021-04-16

  网络出版日期: 2021-05-08

基金资助

国家自然科学基金(21772023); 国家自然科学基金(21901041)

收起

Phosphine Oxide-Directed Palladium-Catalyzed Heck-Type Functionalization of o-Carboranes

  • Lingxiang Lian ,
  • Jingyi Yin ,
  • Caixia Lin ,
  • Keyin Ye ,
  • Yaofeng Yuan
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  • College of Chemistry, Fuzhou University, Fuzhou 350108
*Corresponding authors. E-mail: ;
E-mail:

Received date: 2021-03-06

  Revised date: 2021-04-16

  Online published: 2021-05-08

Supported by

National Natural Science Foundation of China(21772023); National Natural Science Foundation of China(21901041)

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摘要

邻-碳硼烷的选择性官能团化是碳硼烷化学中的一个热点. 由于邻-碳硼烷特殊的三维芳香性, 其在聚集诱导发光材料、非线性发光材料以及其他功能材料领域有着广泛的应用. 在邻碳硼烷上引入π-共轭体系能进一步扩大其在发光材料领域的应用. 报道了膦氧导向钯催化邻碳硼烷Heck类型的单烯基化反应.

关键词： 钯; Heck反应; 碳硼烷; B—H活化

本文引用格式

连凌翔 , 尹静怡 , 林彩霞 , 叶克印 , 袁耀锋 . 膦氧导向钯催化邻碳硼烷Heck类型的官能团化反应[J]. 有机化学, 2021 , 41(8) : 3249 -3255 . DOI: 10.6023/cjoc202103015

Abstract

The selective functionalization of o-carboranes is a popular topic in carborane chemistry. o-Carborane has been widely used in aggregation-induced luminescent materials, nonlinear luminescent materials and other function materials due to its special 3D-aromaticity. The π conjugated systems-tethered o-carboranes could further broaden its applications in the field of luminescent materials. Herein, we have developed a palladium-catalyzed Heck-type mono-alkenylation of o-carboranes featuring phosphine oxide as the directing group.

Key words： palladium; Heck reaction; carborane; B—H activation

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