研究论文

锰催化的碳酸乙烯亚乙酯对喹唑啉酮的C—H烯丙基化

  • 李玉东 ,
  • 李莹 ,
  • 董亚楠 ,
  • 夏春谷 ,
  • 李跃辉
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  • a 中国科学院兰州化学物理研究所苏州研究院 羰基合成与选择氧化国家重点实验室 兰州 730000
    b 中国科学院大学 北京 100049

收稿日期: 2021-10-02

  修回日期: 2021-10-30

  网络出版日期: 2021-11-10

基金资助

国家自然科学基金(22022204); 国家自然科学基金(21633013); 国家自然科学基金(22072167)

Manganese-Catalyzed Allylation of Quinazolinones with 4-Vinyl-1,3-dioxolan-2-one via C—H Activation

  • Yudong Li ,
  • Ying Li ,
  • Ya'nan Dong ,
  • Chungu Xia ,
  • Yuehui Li
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  • a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000
    b University of Chinese Academy of Sciences, Beijing 100049
* Corresponding authors. E-mail: ;

Received date: 2021-10-02

  Revised date: 2021-10-30

  Online published: 2021-11-10

Supported by

National Natural Science Foundation of China(22022204); National Natural Science Foundation of China(21633013); National Natural Science Foundation of China(22072167)

摘要

以碳酸乙烯亚乙酯为原料, 通过锰催化的喹唑啉酮的邻位碳氢烯丙基化反应, 制备得到了一系列具有潜在应用价值的芳基丁烯醇类产物. 该反应表现出较好的底物普适性和顺反立体选择性, 拓展了锰催化C—C偶联反应的类型.

本文引用格式

李玉东 , 李莹 , 董亚楠 , 夏春谷 , 李跃辉 . 锰催化的碳酸乙烯亚乙酯对喹唑啉酮的C—H烯丙基化[J]. 有机化学, 2022 , 42(3) : 847 -853 . DOI: 10.6023/cjoc202110002

Abstract

The ortho-allylation of quinazolinones with 4-vinyl-1,3-dioxolan-2-one via manganese catalysis has been described. A series of allylation products with potential applications have been obtained. This protocol is also highlighted by good compatibility of functional groups and excellent E/Z selectivity. This work broadens the scope of Mn-catalyzed C—C coupling reactions.

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