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2022 , Vol. 42 >Issue 2: 534 - 542

DOI: https://doi.org/10.6023/cjoc202107024

研究论文

Ag-Cu负载的胺基石墨烯催化β-羟基-1,2,3-三唑绿色合成研究

  • 黄强 ,
  • 邓婷婷 ,
  • 朱佳运 ,
  • 李军 ,
  • 黎飞飞
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  • a 遵义医科大学药学院 贵州遵义 563000
    b 遵义医科大学基础药理教育部重点实验室 贵州遵义 563000

收稿日期: 2021-07-10

  修回日期: 2021-09-27

  网络出版日期: 2022-02-24

基金资助

遵义医科大学2018年学术新苗培养及创新探索专项([2018]5772-013); 遵义医科大学2018年学术新苗培养及创新探索专项(CK-1149-011); 贵州省普通高等学校青年科技人才成长(KY[2021]221)

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Study on the Green Synthesis of β-Hydroxy-1,2,3-triazoles Catalyzed by An Amino-Functionalized Graphene-Supported Ag-Cu Composites

  • Qiang Huang ,
  • Tingting Deng ,
  • Jiayun Zhu ,
  • Jun Li ,
  • Feifei Li
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  • a School of Pharmacy, Zunyi Medical University, Zunyi, Guizhou 563000
    b Key Laboratory of Basic Pharmacology of Ministry of Education, Zunyi Medical University, Zunyi, Guizhou 563000
* Corresponding author. E-mail:

Received date: 2021-07-10

  Revised date: 2021-09-27

  Online published: 2022-02-24

Supported by

Academic Cultivation and Innovation Exploration Special Project of Zunyi Medical University in 2018([2018]5772-013); Academic Cultivation and Innovation Exploration Special Project of Zunyi Medical University in 2018(CK-1149-011); Young Talents Growth Project of the Higher Education Institutions of Guizhou Province(KY[2021]221)

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摘要

开发了一种Ag-Cu双金属负载的胺基石墨烯催化剂用于1,2,3-三唑类化合物的合成. 利用各种技术对催化剂进行了表征, 催化剂活性测试表明, 该催化剂在温和反应条件下具有高催化活性、好的循环稳定性和易分离的特点. 水作为绿色溶剂, 反应收率高. 该方法为β-羟基-1,2,3-三唑类化合物的水相绿色合成提供了一种可替代的多相催化策略, 具有重要的科学价值.

关键词： 石墨烯; 催化剂; 1,2,3-三唑; 点击化学; 多相催化

本文引用格式

黄强 , 邓婷婷 , 朱佳运 , 李军 , 黎飞飞 . Ag-Cu负载的胺基石墨烯催化β-羟基-1,2,3-三唑绿色合成研究[J]. 有机化学, 2022 , 42(2) : 534 -542 . DOI: 10.6023/cjoc202107024

Abstract

An amino-functionalized graphene-immobilized Ag-Cu composite (Ag-Cu/GO-NH2) was synthesized. The properties of the prepared catalyst were analyzed using various techniques, that showed high catalytic activity, good recyclability, and easy separability in the green synthesis of β-hydroxy-1,2,3-triazole derivatives under mild reaction conditions resulting in good to excellent yields. It provided an alternative heterogeneous catalytic strategy for the green synthesis of β-hydroxy- 1,2,3-triazoles in water, which had an important scientific significance.

Key words： graphene; catalyst; 1,2,3-triazoles; click chemistry; heterogeneous catalysis

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