芳基乙烯β-H区域选择性三氟甲基磺酰化反应
收稿日期: 2022-02-11
修回日期: 2022-04-06
网络出版日期: 2022-04-15
基金资助
江苏省高校自然科学研究项目(18KJA150004); 大学生创新创业训练计划项目和江苏省高校品牌专业资助项目
β-H Regioselective Trifluoromethyl Sulfonylation of Aryl Ethylene
Received date: 2022-02-11
Revised date: 2022-04-06
Online published: 2022-04-15
Supported by
Natural Science Foundation of the Jiangsu Higher Education Institutions of China(18KJA150004); Undergraduate Innovation and Entrepreneurship Training Program and the Brand Major of Universities in Jiangsu Province
徐琳琳 , 兰美君 , 张慕雨 , 张永琪 , 冯宇豪 , 荣良策 , 张金鹏 . 芳基乙烯β-H区域选择性三氟甲基磺酰化反应[J]. 有机化学, 2022 , 42(7) : 2134 -2139 . DOI: 10.6023/cjoc202202014
In the presence of cerium ammonium nitrate, the β-H radical sulfonation reaction of aryl ethylene with sodium trifluoromethanesulfinate was reported to give highly regioselective trans-alkene. The advantages of this method were cheap and easy to obtain reaction reagents, mild reaction conditions and simple operation. Moreover, the reaction had a high regioselective and configurational selectivity.
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