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2022 , Vol. 42 >Issue 8: 2568 - 2573

DOI: https://doi.org/10.6023/cjoc202202008

研究论文

可见光诱导甲酸盐参与的烯烃氢羧化反应

  • 黄燕 ,
  • 张谦 ,
  • 詹乐武 ,
  • 侯静 ,
  • 李斌栋
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  • 南京理工大学化学与化工学院 南京 210094
† 共同第一作者

收稿日期: 2022-02-08

  修回日期: 2022-04-11

  网络出版日期: 2022-04-22

基金资助

国家自然科学基金(21901118); 江苏省自然科学基金(BK20190430); 重点高校基础科研业务费专项资金(30921011206)

收起

Hydrocarboxylation of Alkenes with Formate Salts via Photocatalysis

  • Yan Huang ,
  • Qian Zhang ,
  • Lewu Zhan ,
  • Jing Hou ,
  • Bindong Li
Expand
  • College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
† These authors contributed equally to this work.
* E-mail: ;

Received date: 2022-02-08

  Revised date: 2022-04-11

  Online published: 2022-04-22

Supported by

National Natural Science Foundation of China(21901118); Natural Science Foundation of Jiangsu Province(BK20190430); Fundamental Research Funds for the Central Universities(30921011206)

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摘要

发展了一种温和条件下以甲酸盐作为还原剂和羰基来源的β-选择性烯烃氢羧化反应. 利用该方法, 一系列的烯烃能够被有效地转化为高价值的羧酸产品. 该方法具备催化剂用量小、官能团耐受性好、易于放大等特点.

关键词： 烯烃; 氢羧化; 光催化; 二氧化碳自由基负离子; 甲酸盐

本文引用格式

黄燕 , 张谦 , 詹乐武 , 侯静 , 李斌栋 . 可见光诱导甲酸盐参与的烯烃氢羧化反应[J]. 有机化学, 2022 , 42(8) : 2568 -2573 . DOI: 10.6023/cjoc202202008

Abstract

A transition-metal-free β-selective hydrocarboxylation of alkenes under mild conditions has been developed using a formate salt as the reductant, carbonyl source. A broad range of alkenes were compatible with this method and can be efficiently converted into value-added carboxylic acid products. This method also features low catalyst loading, good functional group tolerance, and easy scalability.

Key words： alkenes; hydrocarboxylation; photocatalysis; carbon dioxide radical anion; formate salt

参考文献

[1]
Kiss, G. Chem. Rev. 2001, 101, 3435.
[2]
Wu, X.-F.; Fang, X.-J.; Wu, L.-P.; Jackstell, R.; Neumann, H.; Beller, M. Acc. Chem. Res. 2014, 47, 1041.
[3]
Hou, Y.; Niu, M.; Wu, W. Ind. Eng. Chem. Res. 2020, 59, 16899.
[4]
Ra, E.-C.; Kim, K.-Y.; Kim, E.-H.; Lee, H.; An, K.; Lee. J.-S. ACS Catal. 2020, 10, 11318.
[5]
Tortajada, A.; Juliá-Hernández, F.; Börjesson, M.; Moragas, T.; Martin, R. Angew. Chem. Int. Ed. 2018, 57, 15948.
[6]
Wu, L.-P.; Liu, Q.; Jackstell, R.; Beller, M. Angew. Chem. Int. Ed. 2014, 53, 6310.
[7]
Hendy, C.-M.; Smith, G.-C.; Xu, Z.-H.; Lian, T.-Q.; Jui, N.-T. J. Am. Chem. Soc. 2021, 143, 8987.
[8]
Chmiel, A.-F.; Williams, O.-P.; Chernowsky, C.-P.; Yeung, C.-S.; Wickens. Z.-K. J. Am. Chem. Soc. 2021, 143, 10882.
[9]
Alektiar, S.-N.; Wickens. Z.-K. J. Am. Chem. Soc. 2021, 143, 13022.
[10]
Koppenol, W.-H.; Rush, J.-D. J. Phys. Chem. 1987, 91, 4429.
[11]
Huang, Y.; Hou, J.; Zhan, L.-W.; Zhang, Q.; Tang, W.-Y.; li, B.-D. ACS Catal. 2021, 11, 15004.
[12]
Péault, L.; Planchat, A.; Nun, P.; Grognec, E.-L; Coeffard. V. J. Org. Chem. 2021, 86, 18192.
[13]
Liu, W.; Ren, W.-L.; Li, J.-F.; Shi, Y.; Chang, W.-J.; Shi, Y. Org. Lett. 2017, 19, 1748.
[14]
Guđmundsson, A.; Gustafson, K.-P.-J.; Mai, B.-K.; Yang, B.; Himo, F.; Bäckvall, J.-E. ACS Catal. 2018, 8, 11134.
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