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2022 , Vol. 42 >Issue 9: 2659 - 2681

DOI: https://doi.org/10.6023/cjoc202204007

综述与进展

过渡金属催化的异腈插入反应研究进展

  • 高秋珊 ,
  • 李蒙 ,
  • 伍婉卿
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  • a 华南理工大学化学与化工学院 广东省功能分子工程重点实验室 广州 510640
    b 黄河生态环境科学研究所 郑州 450004
† 共同第一作者

收稿日期: 2022-04-13

  修回日期: 2022-06-10

  网络出版日期: 2022-06-23

基金资助

国家自然科学基金(22071063)

收起

Recent Advances in Transition Metal-Catalyzed Isocyanide Insertion Reactions

  • Qiushan Gao ,
  • Meng Li ,
  • Wanqing Wu
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  • a Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640
    b Yellow River Institute of Eco-environmental Science, Zhengzhou 450004
† These authors contributed equally to this work
* Corresponding author. E-mail:

Received date: 2022-04-13

  Revised date: 2022-06-10

  Online published: 2022-06-23

Supported by

National Natural Science Foundation of China(22071063)

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摘要

作为一类含(NC)官能团的高活性有机小分子, 异腈在有机合成、材料化学、配位化学等领域有着非常广泛的应用. 近年来, 过渡金属催化的异腈插入反应由于具有操作简便、成键高效、反应选择性好等优点, 引起了化学家们的关注, 并且通过该类型反应成功构建了一系列十分有用的链状或环状化合物, 例如官能化的酮、酰胺、氮杂环化合物等. 为了更及时地了解该领域的研究进展, 根据金属类别的不同, 对2017至2021年过渡金属催化的异腈插入反应进行了概括和总结, 并对该领域的发展前景进行了展望.

关键词： 过渡金属催化; 异腈; 插入反应; 氮杂环化合物

本文引用格式

高秋珊 , 李蒙 , 伍婉卿 . 过渡金属催化的异腈插入反应研究进展[J]. 有机化学, 2022 , 42(9) : 2659 -2681 . DOI: 10.6023/cjoc202204007

Abstract

As a class of small organic molecules containing (NC) functional groups with high activity, isocyanide has been widely employed in organic synthesis, materials science, as well as coordination chemistry. In recent years, the transition metal-catalyzed isocyanide insertion reactions have attracted much attention due to the convenient and simple operations, the efficiency in the formation of diverse new bonds and good reaction selectivity. A series of highly useful chain or cyclic compounds have been successfully constructed using this strategy, such as functionalized ketones, amides, nitrogen heterocyclic compounds, etc. To study the most recent progress, the advances in transition metal-catalyzed isocyanide insertion reactions since 2017 to 2021 are briefly summarized according to different metal categories, and the future development has also been prospected in this review.

Key words： transition metal-catalysis; isocyanide; insertion reactions; nitrogen heterocyclic compounds

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