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2022 , Vol. 42 >Issue 10: 3335 - 3350

DOI: https://doi.org/10.6023/cjoc202205032

综述与进展

手性Lewis酸催化的可见光不对称合成研究进展

  • 成秀亮 ,
  • 李冬 ,
  • 杨博轩 ,
  • 林玉妹 ,
  • 龚磊
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  • a 厦门大学化学化工学院 福建省化学生物学重点实验室 福建厦门 361005
    b 福建省能源材料科学与技术创新实验室(IKKEM) 福建厦门 361005
†共同第一作者.

收稿日期: 2022-05-19

  修回日期: 2022-06-25

  网络出版日期: 2022-07-05

基金资助

国家自然科学基金(22071209); 国家自然科学基金(22071206); 及国家高层次青年人才资助项目

收起

Recent Advances in Visible-Light Photocatalytic Asymmetric Synthesis Enabled by Chiral Lewis Acids

  • Xiuliang Cheng ,
  • Dong Li ,
  • Boxuan Yang ,
  • Yumei Lin ,
  • Lei Gong
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  • a College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Biology of Fujian Province, Xiamen University, Xiamen, Fujian 361005
    b Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian 361005
†These authors contributed equally to this work.
* Corresponding author. E-mail:

Received date: 2022-05-19

  Revised date: 2022-06-25

  Online published: 2022-07-05

Supported by

National Natural Science Foundation of China(22071209); National Natural Science Foundation of China(22071206); National Youth Talent Support Program

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摘要

近年来, 可见光催化不对称合成已在快速构筑结构多样的光活性有机分子上展现了相当的潜力. 手性Lewis酸(CLA), 如手性硼烷化合物、镧系配合物、第一过渡系金属配合物、金属中心手性铱及铑配合物等, 能有效控制可见光驱动自由基反应过程的立体化学. 按照手性Lewis酸双功能催化和手性Lewis酸/可见光催化剂协同催化这两种主要反应类型, 简要介绍了这一领域的最新进展, 以期促进有机合成、光催化、不对称催化领域的发展.

关键词： 可见光催化; 不对称合成; 手性Lewis酸; 协同催化; 双功能催化

本文引用格式

成秀亮 , 李冬 , 杨博轩 , 林玉妹 , 龚磊 . 手性Lewis酸催化的可见光不对称合成研究进展[J]. 有机化学, 2022 , 42(10) : 3335 -3350 . DOI: 10.6023/cjoc202205032

Abstract

In recent years, visible-light photocatalytic asymmetric synthesis has shown considerable potential in the mild and rapid construction of optically active organic molecules with structural diversity. Chiral Lewis acids (CLA), including chiral borane compounds, lanthanum complexes, first-row transition metal complexes, and chiral-at-iridium or rhodium complexes, have been established as one class of the most effective catalysts being capable of controlling the stereochemistry in photo-induced chemical transformations. The recent advances in this emerging field were presented by classifying the reactions into bifunctional CLA photocatalytic reactions and reactions enabled by dual catalysis with a CLA catalyst and an external photosensitizer, expecting that these studies will stimulate progress in organic synthesis, photocatalysis and asymmetric catalysis.

Key words： visible light photocatalysis; asymmetric synthesis; chiral Lewis acid; cooperative catalysis; bifunctional catalysis

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