碘化钾介导的电催化N-酰基/磺酰基次磺酰胺的合成
收稿日期: 2022-05-18
修回日期: 2022-07-01
网络出版日期: 2022-07-21
基金资助
国家自然科学基金(21702175); 国家自然科学基金(21961037); 国家自然科学基金(22161044); 新疆维吾尔自治区天山创新团队(2021D14011); 新疆维吾尔自治区自然科学基金(2020D01C077)
Electrochemical Synthesis of N-Acyl/Sulfonylsulfenamides Using Potassium Iodide as Mediator
Received date: 2022-05-18
Revised date: 2022-07-01
Online published: 2022-07-21
Supported by
National Natural Science Foundation of China(21702175); National Natural Science Foundation of China(21961037); National Natural Science Foundation of China(22161044); Program for Tianshan Innovative Research Team of Xinjiang Uygur Autonomous Region(2021D14011); Natural Science Foundation of Xinjiang Uygur Autonomous Region(2020D01C077)
魏兆鑫 , 王仁杰 , 张永红 , 王斌 , 夏昱 , 金伟伟 , 刘晨江 . 碘化钾介导的电催化N-酰基/磺酰基次磺酰胺的合成[J]. 有机化学, 2022 , 42(11) : 3730 -3739 . DOI: 10.6023/cjoc202205026
An efficient and environmentally friendly electrocatalytic protocol has been developed for synthesizing N-acyl/ sulfonyl sulfenamides. In an undivided cell, various electron-deficient groups substituted amines and aryl thiols react smoothly to afford the N—S bond formation products in 36%~98% yields. Preliminary mechanistic studies indicate that the reaction may work through a free radical process.
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