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2023 , Vol. 43 >Issue 1: 36 - 56

DOI: https://doi.org/10.6023/cjoc202206050

综述与进展

直接三氟甲硒基化反应研究进展

  • 胡朝明 ,
  • 吴纪红 ,
  • 吴晶晶 ,
  • 吴范宏
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  • 上海应用技术大学化学与环境工程学院 上海绿色氟代制药工程技术研究中心 上海 201418

收稿日期: 2022-06-27

  修回日期: 2022-08-02

  网络出版日期: 2022-09-02

基金资助

国家自然科学基金(21672151); 国家自然科学基金(21602136)

收起

Research Progress on Direct Trifluoromethylselenylation

  • Zhaoming Hu ,
  • Jihong Wu ,
  • Jingjing Wu ,
  • Fanhong Wu
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  • Shanghai Engineering Research Center of Green Fluoropharmaceutical Technology, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418
* Corresponding authors. E-mail: ;

Received date: 2022-06-27

  Revised date: 2022-08-02

  Online published: 2022-09-02

Supported by

National Natural Science Foundation of China(21672151); National Natural Science Foundation of China(21602136)

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摘要

三氟甲硒基化反应是近几年继三氟甲硫基化反应后的又一重要研究课题, 由于三氟甲硒基同时包含氟和硒这两种重要的化学元素, 并且含三氟甲硒基的化合物具有重要的潜在生物活性, 因此近年来越来越多的科研工作者开始把目光转向这一新兴基团. 此综述按照亲核三氟甲硒基化反应、亲电三氟甲硒基化反应、自由基三氟甲硒基化反应三种反应类型, 对近6年来的国内外学者在直接三氟甲硒基化反应的研究进行了全面总结, 并对部分反应机理进行详细的论述, 最后对直接三氟甲硒基化反应进行了总结和展望.

关键词： 三氟甲硒基; 亲核反应; 亲电反应; 自由基反应

本文引用格式

胡朝明 , 吴纪红 , 吴晶晶 , 吴范宏 . 直接三氟甲硒基化反应研究进展[J]. 有机化学, 2023 , 43(1) : 36 -56 . DOI: 10.6023/cjoc202206050

Abstract

The trifluoromethylselenylation reaction is another important research topic after trifluoromethylsulfanylation reaction in recent years. Because the trifluoromethylselenyl group contains two important chemical elements, fluorine and selenium, and the compounds containing trifluoromethyl selenide have important potential biological activities, more and more researchers begin to turn their attention to this new group in recent years. In this paper, according to the three reaction types of nucleophilic trifluoromethylselenylation reaction, electrophilic trifluoromethylselenylation reaction and radical trifluoromethylselenylation reaction, the research results of domestic and foreign scholars on direct trifluoromethylselenylation reaction in recent 6 years are comprehensively summarized, and some reaction mechanisms are discussed in detail. Finally, the direct trifluoromethylselenylation reaction is summarized and prospected.

Key words： trifluoromethylseleno; nucleophilic reaction; electrophilic reaction; radical reaction

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