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2023 , Vol. 43 >Issue 2: 777 - 780

DOI: https://doi.org/10.6023/cjoc202207030

研究简报

一类新型卤化偕二硼试剂的合成

  • 方通昌 ,
  • 徐良轩 ,
  • 秦玉承 ,
  • 姜南权 ,
  • 刘超
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  • a 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000
    b 中国科学院大学 北京 100049

收稿日期: 2022-07-23

  修回日期: 2022-08-17

  网络出版日期: 2022-09-09

基金资助

国家自然科学基金(22022113)

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A Novel Synthesis of Halogenated gem-Diboron Reagents

  • Tongchang Fang ,
  • Liangxuan Xu ,
  • Yucheng Qin ,
  • Nanquan Jiang ,
  • Chao Liu
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  • a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
    b University of Chinese Academy of Sciences, Beijing 100049
* Corresponding author. E-mail:

Received date: 2022-07-23

  Revised date: 2022-08-17

  Online published: 2022-09-09

Supported by

National Natural Science Foundation of China(22022113)

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摘要

开发了一种新型偕二硼试剂-卤化偕二硼酸酯[X-CR(Bpin)2], 该试剂性状稳定且易于大规模制备; 当使用烷基取代的偕二卤化物时, 可以高收率地制备四取代的卤代偕二硼酸酯, 为偕二硼试剂化学的开发提供了新的选择.

关键词： 元素有机化学; 试剂化学; 有机硼; 偕二硼

本文引用格式

方通昌 , 徐良轩 , 秦玉承 , 姜南权 , 刘超 . 一类新型卤化偕二硼试剂的合成[J]. 有机化学, 2023 , 43(2) : 777 -780 . DOI: 10.6023/cjoc202207030

Abstract

A novel synthesis of halogenated gem-diboronates (X-CR(Bpin)2) was developed. The reagents are stable and easy to prepare in a large scale. Tetra-substituted halogenated gem-diboronates can be prepared in high yields when using alkyl- substituted gem-dihalides, providing a new strategy for the synthesis of new gem-diboron compounds.

Key words： element-organic chemistry; reagent chemistry; organoboron; gem-diboron

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