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2023 , Vol. 43 >Issue 4: 1416 - 1434

DOI: https://doi.org/10.6023/cjoc202208004

综述与进展

电化学固定CO2构建羧酸衍生物的研究进展

  • 潘永周 ,
  • 蒙秀金 ,
  • 王迎春 ,
  • 何慕雪
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  • a 桂林医学院公共卫生学院 广西环境暴露组学与全生命周期健康重点实验室 广西桂林 541199
    b 广西师范大学化学与药学学院 省部共建药用资源化学与药物分子工程国家重点实验室 广西桂林 541004
    c 吉首大学化学化工学院 湖南吉首 416000

收稿日期: 2022-08-03

  修回日期: 2022-10-11

  网络出版日期: 2022-11-15

基金资助

广西自然科学基金(2022GXNSFBA035489); 广西自然科学基金(2021GXNSFBA196041); 中央引导地方科技发展资金项目(桂科ZY21195014); “武陵山地区民族药解析与创制湖南省工程实验室”开放课题(hgxy2101)

收起

Recent Progress in Electrochemical Fixation of CO2 to Construct Carboxylic Acid Derivatives

  • Yongzhou Pan ,
  • Xiujin Meng ,
  • Yingchun Wang ,
  • Muxue He
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  • a Guangxi Key Laboratory of Environmental Exposomics and Entire Lifecycle Health, School of Public Health, Guilin Medical University, Guilin, Guangxi 541199
    b State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, Guangxi 541004
    c College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hunan 416000
* Corresponding author.

Received date: 2022-08-03

  Revised date: 2022-10-11

  Online published: 2022-11-15

Supported by

Natural Science Foundation of Guangxi Province(2022GXNSFBA035489); Natural Science Foundation of Guangxi Province(2021GXNSFBA196041); Central Government Guides Local Science and Technology Development Fund Projects(guike ZY21195014); Opening Project of Hunan Engineering Laboratory for Analyse and Drugs Development of Ethnomedicine in Wuling Mountain(hgxy2101)

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摘要

CO2由于其含量丰富、无毒和低成本等特性可作为有机合成中的重要C1源, 因此, 使用CO2作为C1源合成高附加值的化合物具有重要的意义. 本综述重点介绍了在电化学条件下使用CO2作为亲电试剂参与有机化合物羧化反应的最新进展. 主要介绍了非活化有机卤化物、不饱和烯烃化合物和一些特殊化合物的电化学羧化, 并就使用和不使用牺牲阳极进行了详细分类, 讨论了这些反应的反应机制, 为今后此类反应在有机合成中的应用提供参考.

关键词： 二氧化碳; 羧化; 羧酸衍生物; 电化学合成

本文引用格式

潘永周 , 蒙秀金 , 王迎春 , 何慕雪 . 电化学固定CO2构建羧酸衍生物的研究进展[J]. 有机化学, 2023 , 43(4) : 1416 -1434 . DOI: 10.6023/cjoc202208004

Abstract

CO2 is an important C1 source in organic synthesis due to its abundant, non-toxic and low-cost properties. There- fore, it is of great significance to use CO2 as a C1 source to synthesize compounds with high added value. This review focuses on the recent progress in the carboxylation of organic compounds using CO2 as an electrophile under electrochemical conditions. The electrochemical carboxylation of non-activated organic halides, unsaturated alkene compounds and some special compounds are mainly introduced. And the use of sacrificial anodes and non-sacrificial anodes is classified in detail. The reaction mechanisms of these reactions are also discussed. This review provides a reference for the application of such reactions in organic synthesis in the future.

Key words： carbon dioxide; carboxylation; carboxylic acid derivatives; electrochemical synthesis

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