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2023 , Vol. 43 >Issue 6: 2002 - 2025

DOI: https://doi.org/10.6023/cjoc202211006

综述与进展

钳形氮杂环卡宾金属络合物的研究进展

  • 杨亮茹 ,
  • 郭梦丽 ,
  • 袁金伟 ,
  • 王佳美 ,
  • 夏宇婷 ,
  • 肖咏梅 ,
  • 毛璞
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  • 河南工业大学化学化工学院 郑州 450001

收稿日期: 2022-11-07

  修回日期: 2022-12-19

  网络出版日期: 2023-01-12

基金资助

河南省科技厅自然科学基金(212102310332); 河南省留学人员科技活动择优资助、河南工业大学河南省省属高校基本科研业务费专项基金(2017RCJH08); 河南工业大学创新基金支持计划专项(2020ZKCJ29)

收起

Research Progress on Pincer N-Heterocyclic Carbene Metal Complexes

  • Liangru Yang ,
  • Mengli Guo ,
  • Jinwei Yuan ,
  • Jiamei Wangx ,
  • Yuting Xia ,
  • Yongmei Xiao ,
  • Pu Mao
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  • School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001
* E-mail: ;

Received date: 2022-11-07

  Revised date: 2022-12-19

  Online published: 2023-01-12

Supported by

Natural Science Foundation of Department of Science and Technology of Henan Province(212102310332); Merit Funding for the Oversea Staff of Henan Province, the Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology(2017RCJH08); Innovative Funds Plan of Henan University of Technology(2020ZKCJ29)

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摘要

氮杂环卡宾作为一类结构和性质特殊且便于调控的新型配体, 近年来备受研究者关注. 结构多样、性能各异的多种氮杂环卡宾金属络合物也被广泛合成, 并被应用于催化、合成、材料、医药等领域. 综述了近年来含N、P、S、O、Se等杂原子配位及不同杂化态C的钳形氮杂环卡宾金属络合物的合成及应用研究进展.

关键词： 氮杂环卡宾; 钳形金属络合物; 合成; 应用

本文引用格式

杨亮茹 , 郭梦丽 , 袁金伟 , 王佳美 , 夏宇婷 , 肖咏梅 , 毛璞 . 钳形氮杂环卡宾金属络合物的研究进展[J]. 有机化学, 2023 , 43(6) : 2002 -2025 . DOI: 10.6023/cjoc202211006

Abstract

As a type of novel ligands featuring special structure and properties that can be easily regulated, N-heterocyclic carbenes (NHCs) have attracted much research attention in recent years. Various NHC metal complexes with typical structure and properties have been synthesized and utilized widely in the fields of catalysis, synthesis, materials, pharmaceuticals, etc. Here, recent research progress on the synthesis and applications of pincer NHC metal complexes containing heteroatoms of N, P, S, O, Se, etc. and C featuring different hybrid state is summarized.

Key words： N-heterocyclic carbene; pincer metal complex; synthesis; application

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