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2023 , Vol. 43 >Issue 7: 2425 - 2446

DOI: https://doi.org/10.6023/cjoc202212035

综述与进展

基于热、光以及电化学过程的无过渡金属碳-氢键硫氰化和硒氰化反应

  • 徐忠荣 ,
  • 万结平 ,
  • 刘云云
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  • a江西师范大学化学化工学院 南昌 330022
    b南京林业大学林产化学与材料国际创新高地 南京 210037

收稿日期: 2022-12-28

  修回日期: 2023-01-23

  网络出版日期: 2023-02-07

基金资助

国家自然科学基金(22261026)

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Transition Metal-Free C—H Thiocyanation and Selenocyanation Based on Thermochemical, Photocatalytic and Electrochemical Process

  • Zhongrong Xu ,
  • Jieping Wan ,
  • Yunyun Liu
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  • aCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022
    bInternational Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037
*E-mail: ;

Received date: 2022-12-28

  Revised date: 2023-01-23

  Online published: 2023-02-07

Supported by

National Natural Science Foundation of China(22261026)

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摘要

硫氰基和硒氰基均在有机合成中具有广泛应用的重要官能团. 这类结构也经常出现在具有生物药物活性、光学活性以及催化功能的分子中. 因此, 发展可用于合成具有结构多样性的有机硫氰化和硒氰化物及相关串联转化合成多样性杂环分子的方法持续吸引着研究者的兴趣, 总结了无过渡金属条件下的碳-氢键的硫氰化和硒氰化反应合成有机硫氰化物和硒氰化物以及相关串联环化反应的研究进展.

关键词： 无过渡金属; 碳-氢键; 硫氰化; 硒氰化; 热化学; 光催化

本文引用格式

徐忠荣 , 万结平 , 刘云云 . 基于热、光以及电化学过程的无过渡金属碳-氢键硫氰化和硒氰化反应[J]. 有机化学, 2023 , 43(7) : 2425 -2446 . DOI: 10.6023/cjoc202212035

Abstract

Thiocyano and selenocyano are both important functional groups with broad application in organic synthesis. Such functional structures also occur frequently in molecules possessing valuable biological and pharmaceutical activities, optical functions, and catalytic profiles. Therefore, developing synthetic methods toward diverse organo thio-/selenocyanates as well as the tandem annulation for the construction of diverse heterocyclic scaffolds keep receiving high interests. The advances on the synthesis of organo thio-/selenocyanates via transition metal-free C—H thiocyanation or selenocyanation as well as the tandem annulation reactions based on such C—H functionalization are reviewed.

Key words： transition metal-free; C—H bond; thiocyanation; selenocyanation; thermochemistry; photocatalysis

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