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2023 , Vol. 43 >Issue 3: 924 - 948

DOI: https://doi.org/10.6023/cjoc202211039

综述与进展

配体在Cp*Rh(III)催化C—H键官能团化反应中的应用

  • 潘彦年 ,
  • 秦萧 ,
  • 袁成凯 ,
  • 鲁艺
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  • 南京大学化学化工学院 南京 210023

收稿日期: 2022-11-29

  修回日期: 2023-02-06

  网络出版日期: 2023-02-15

基金资助

国家自然科学基金(21671097); 中央高校基本科研业务费专项资金资助项目

收起

Application of Ligands in Cp*Rh(III)-Catalyzed C—H Bond Functionalization Reaction

  • Yannian Pan ,
  • Xiao Qin ,
  • Chengkai Yuan ,
  • Yi Lu
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  • School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023
* Corresponding author. E-mail:

Received date: 2022-11-29

  Revised date: 2023-02-06

  Online published: 2023-02-15

Supported by

National Natural Science Foundation of China(21671097); Fundamental Research Funds for the Central Universities

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摘要

Cp*Rh(III)催化剂因其优异的催化活性、稳定性以及反应条件温和性, 在惰性C—H键官能团化领域有着广泛的应用. 然而, 由于Rh(III)配位轨道数量的限制, 针对Cp*Rh(III)催化体系的外加配体研究相对较少. 近年来, 本课题组致力于通过外加配体来促进Cp*Rh(III)对C—H键的官能团化, 并进一步对产物的选择性进行调控. 系统地总结了由配体促进的Cp*Rh(III)催化C—H键官能团化反应的相关工作, 包括非手性活化和手性活化, 概述了配体在催化体系中所起到的作用, 并对部分反应机理进行了简要描述.

关键词： Cp*Rh(III); C—H键官能团化; 配体

本文引用格式

潘彦年 , 秦萧 , 袁成凯 , 鲁艺 . 配体在Cp*Rh(III)催化C—H键官能团化反应中的应用[J]. 有机化学, 2023 , 43(3) : 924 -948 . DOI: 10.6023/cjoc202211039

Abstract

Cp*Rh(III) catalysts have shown excellent performance in the field of inert C—H bond functionalization because of their high activity and stability under mild conditions. However, limited by the number of Rh(III) coordination orbitals, the ligand studies in Cp*Rh(III) catalytic system are relatively few. Recently, our research group has been focusing on the external ligands promoted C—H bond functionalization with high activity and selectivity. In this review, the related works of Cp*Rh(III) catalyzed C—H bond functionalization are systematically summarized, including both symmetric and asymmetric C—H activation, the role of ligands in the Cp*Rh(III) catalytic system is discussed, and some reaction mechanisms are briefly described.

Key words： Cp*Rh(III); C—H bond functionalization; ligands

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