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2023 , Vol. 43 >Issue 8: 2628 - 2646

DOI: https://doi.org/10.6023/cjoc202211020

综述与进展

亚酞菁的合成、性质与应用研究进展

  • 周姝彤 ,
  • 涂胜男 ,
  • 高子健 ,
  • 王叶梅 ,
  • 孙莎莎
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  • 江苏科技大学环境与化学工程学院 江苏镇江 212003

收稿日期: 2022-11-16

  修回日期: 2023-01-27

  网络出版日期: 2023-03-31

基金资助

江苏省自然科学基金(BK20210876); 江苏省高等学校自然科学研究(20KJB150013)

收起

Research Progress in Synthesis, Properties and Application of Subphthalocyanine

  • Shutong Zhou ,
  • Shengnan Tu ,
  • Zijian Gao ,
  • Yemei Wang ,
  • Shasha Sun
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  • School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003
*;

Received date: 2022-11-16

  Revised date: 2023-01-27

  Online published: 2023-03-31

Supported by

The Natural Science Foundation of Jiangsu Province(BK20210876); The Natural Science Foundation of the Jiangsu Higher Education Institutions(20KJB150013)

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摘要

亚酞菁是酞菁缩环衍生物的典型代表, 表现出新颖的锥形结构、优异的发光性质和丰富的可调控性, 是一类有研究前景的新型荧光染料. 研究证明通过对亚酞菁轴向、外围或中心环结构的简单修饰, 可以有效调控其物理化学性质, 如溶解性、吸收/荧光发射、荧光量子产率、单线态氧产率等, 近年来引起了化学工作者的广泛关注. 介绍了亚酞菁的结构、性质和研究意义, 重点综述了亚酞菁的合成、结构和性质的关系及其在生物化学、材料化学和环境化学等领域的应用进展. 最后对亚酞菁的发展现状做了简要总结, 并对亚酞菁的发展进行了展望.

关键词： 亚酞菁; 结构; 光电性质; 应用

本文引用格式

周姝彤 , 涂胜男 , 高子健 , 王叶梅 , 孙莎莎 . 亚酞菁的合成、性质与应用研究进展[J]. 有机化学, 2023 , 43(8) : 2628 -2646 . DOI: 10.6023/cjoc202211020

Abstract

Subphthalocyanine, as a typical contracted analogue of phthalocyanine, exhibits novel cone structure, excellent luminescent properties and high flexibility of modification, which enables it as a new type of fluorescent dye with great research prospects. It has been proved that simple modifications of the axial, peripheral or central ring structure of subphthalocyanine can effectively regulate its physical and chemical properties, such as solubility, absorption/fluorescence emission, fluorescence quantum yield and singlet oxygen yield, and these properties have attracted extensive attentions from chemists in recent years. This review introduces the structures, properties and research significance of subphthalocyanine. Then, the progress in the synthesis, the relationship between properties and molecular structure of subphthalocyanin, and their applications in the area of biochemistry, material chemistry and environmental chemistry are reviewed emphatically. Finally, the development status of subphthalocyanine is summarized, and the further development of subphthalocyanine is discussed and proposed.

Key words： subphthalocyanine; structures; photoelectric properties; application

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